Sorption of thiamethoxam in three Indian soils

The sorption behavior of the insecticide thiamethoxam [3-(2-chloro-1,3-thiazol-5-ylmethyl)-5-methyl-1,3,5-oxadiazinan-4-ylidene(nitro)amine] on three Indian soils with different physico-chemical properties was investigated. The soils represent the major grapevine growing areas of India, where the vineyards frequently receive thiamethoxam applications as foliar spray, soil drenching and through drip irrigation for the management of various insect pests. The rate constants for adsorption and desorption at two different temperatures were obtained from the Lindstrom model, which simultaneously evaluated adsorption and desorption kinetics. The data for rate constants, activation energies, enthalpy of activation, entropy of activation and free energy indicated physical adsorption of thiamethoxam on soil. The adsorptivity of different soils might be attributed to the organic matter and clay contents. A good fit to the linear and Freundlich isotherms was observed for both adsorption as well as desorption. Thiamethoxam could be categorized as a chemical with medium leaching potential.     

Impact of informal regulation of pollution on water quality in rivers in India

In this paper an attempt is made to assess the impact of informal regulation of water pollution on water quality in Indian rivers. For this purpose, an econometric analysis of determinants of water quality in Indian rivers is carried out using water quality (water class) data for 106 monitoring points on 10 important rivers for five years, 1995-1999. To explain variations in water quality, an Ordered Probit model is estimated, in which poll percentage in parliamentary elections, a proxy for the intensity of informal regulation, is taken as one of the main explanatory variables. Rainfall, industrialization, irrigation intensity and fertilizer use are some of the other explanatory variables used in the model to control for the influence of these factors. As expected, river water quality is found to be positively related with rainfall, and negatively related with industrialization, irrigation intensity and fertilizer use. A significant positive relationship is found between poll percentage and water quality, and also between the rate of increase in literacy level in a district and the water quality in rivers flowing through the district. These results point to a significant favorable effect of informal regulation of pollution on water quality in rivers in India.     

Assessment of the Status of Urban Air pollution And Its Impact on Human Health in the City of Kolkata

Air pollution has significant effects on exacerbation of asthma, allergy and other respiratory diseases. Like many other magacities in the world the ambient air quality of Kolkata is also being deteriorated day by day. Automobile exhausts and certain industrial pollutants produce O₃ by photochemical reactions. The particulate matter, particularly less than 10 μ in size, can pass through the natural protective mechanism of human respiratory system and plays an important role in genesis and augmentation of allergic disorders. Sources of air pollution in the area and the unique problem arising out of the emission from the vehicles, industries, etc. have been described. Ambient air quality was monitored along with micrometeorological data and the results are discussed. The status of air pollution in the area has been evaluated and a questionnaire survey was conducted to estimate the allergic symptoms and exposure to assess the respiratory disorders. The data are analysed to evaluate the critical situation arising out of the emission of air pollutants and the impact on human health due to respirable diseases (RDs) to middle class sub-population (activity-wise) in the area are assessed. A strategic air quality management plan has been proposed. For the mitigation of air pollution problems in the city, the different measures to be adopted to maintain the balance between sustainable development and environmental management have been discussed.     

Wastewater management and the east-bound growth of the city of Kolkata: a compatibility analysis

Kolkata, home of 4.5 million people, is generating 1112 million liters of sewage per day and facing the challenge of managing this wastewater. The 125 km² wide wetland on the eastern fringe of the city, popularly known as the East Kolkata Wetlands is serving as a natural sewage treatment plant for more than a century where nearly 78 % of city sewage goes through an intricately designed canal network. This wetland is a designated RAMSAR site where the sewage treatment process is a rare example of an intertwined symbiotic relation between wastewater treatment and wetland aquaculture, where livelihood dependence of the local people on sewage-fed fisheries becomes of strategic importance in sustainable performance of the system. An aggressive urban expansion in the eastern fringe of the city is disturbing this age-old eco-balance by making this sewage water pisciculture less profitable. There is push factor due to reduced attraction of the wastewater fisheries and a pull factor due to emergence of alternative livelihood options through rapid urbanization. To protect wetland in its original form, the civil society and the administrative authorities are designing active interventions. However, these are not generating expected results as these instruments are targeting to mitigate the push factor only without paying much heed to the push–pull interactions.     

Concentrations of some heavy metals in commercially important finfish and shellfish of the River Ganga

Heavy metals are dangerous to aquatic organisms and it can be bioaccumulated in the food chain leading to diseases in human. Cumulative effects of metals or chronic poisoning may occur as a result of long-term exposure even to low concentrations. The accumulation of heavy metals varies depending upon the species, environmental conditions, and inhibitory processes. Concentrations of zinc, copper, lead, and cadmium were determined in finfish and shellfish species in the Gangetic delta using a PerkinElmer Sciex ELAN 5000 ICP mass spectrometer and expressed as milligrams per kilogram of dry weight. In finfish and shellfish species the concentrations of Zn, Cu, Pb, and Cd were comparatively higher at stations 1 and 2 than the permissible level of WHO. The concentration of metals exhibited significant spatial variation and followed the order station 1 > station 2 > station 3 > station 4, which may be related to different degree of contamination in different location. The metal accumulation exhibited species specificity.     

Comparative study of polyhydroxyalkanoates production from acidified and anaerobically treated brewery wastewater using enriched mixed microbial culture

The production of polyhydroxyalkanoates(PHA) from wastewaters using microbial mixed cultures(MMC) has been attracting increased interest because of PHA's biodegradability characteristics. Production of PHA by an MMC enriched with PHA-accumulating bacteria was compared using anaerobically treated and acidified brewery wastewaters under various feeding strategies, namely pulse and batch feed addition. To obtain an enriched MMC, a sequencing batch reactor was inoculated with activated sludge fed with acetate and subjected to aerobic dynamic feeding. The enriched MMC was able to accumulate PHA up to 72.6% of cell dry weight(CDW) with pulse addition of acetate controlled by the dissolved oxygen(DO) concentration in the reactor. In a batch accumulation experiment with acetate,the PHA content achieved(28.5% CDW) was less than that of the pulse feeding strategy with the same amount of acetate(～2000 mg C/L). Using anaerobically treated and acidified brewery wastewater fed in pulses, the maximum PHA accumulated by the enriched MMC was similar for both wastewaters(45% CDW), in spite of the higher volatile fatty acid concentration in acidified brewery wastewater. The pulse feed addition controlled by the DO concentration was difficult to implement for wastewater as compared to acetate because the difference in DO concentration between substrate availability and depletion was low. For the batch addition of acidified wastewater, a slightly lower PHA content(39%CDW) was obtained. These results show that both brewery wastewaters can be utilized for PHA production with a similar maximum PHA storage capacity.     

Narrating place,negotiating history: the politics of place in Land Between the Rivers

Conservation discourses in the last decade have witnessed a radical shift in the conceptualisation of nature. The imagery of a pristine nature has been replaced by a growing recognition of culture and place-based attachments as emerging frontiers of conservation. Yet, the complexities of place and culture call for a greater reflection on cultural approaches to natural resource management. In this paper, I argue that the cultural discourses in conservation policies are largely global in nature and conflict with a community's understanding of a local cultural tradition. The notion of the global closely relates to a global framing of an environmental problem that glosses over cultural specificities. On the other hand, local is defined here in materially specific terms that highlight the role of history in shaping environmental traditions. I examine these contradictory framings through a narrative of conservation, displacement, and cultural loss in a US rural community known as Land Between the Rivers.     

X-ray absorption and photoelectron spectroscopy investigation of selenite reduction by FeII-bearing minerals

The long-lived radionuclide 79Se is one of the elements of concern for the safe storage of high-level nuclear waste, since clay minerals in engineered barriers and natural aquifer sediments strongly adsorb cationic species, but to lesser extent anions like selenate (SeVIO4(2-)) and selenite (SeIVO3(2-)). Previous investigations have demonstrated, however, that SeIV and SeVI are reduced by surface-associated FeII, thereby forming insoluble Se0 and Fe selenides. Here we show that the mixed FeII/III (hydr)oxides green rust and magnetite, and the FeII sulfide mackinawite reduce selenite rapidly (< 1 day) to FeSe, while the slightly slower reduction by the FeII carbonate siderite produces elemental Se. In the case of mackinawite, both S(-II) and FeII surface atoms are oxidized at a ratio of one to four by producing a defective mackinawite surface. Comparison of these spectroscopic results with thermodynamic equilibrium modeling provides evidence that the nature of reduction end product in these FeII systems is controlled by the concentration of HSe(-); Se0 forms only at lower HSe(-) concentrations related to slower HSeO3(-) reduction kinetics. Even under thermodynamically unstable conditions, the initially formed Se solid phases may remain stable for longer periods since their low solubility prevents the dissolution required for a phase transformation into more stable solids. The reduction by Fe2+-montmorillonite is generally much slower and restricted to a pH range, where selenite is adsorbed (pH < 7), stressing the importance of a heterogeneous, surface-enhanced electron transfer reaction. Although the solids precipitated by the redox reaction are nanocrystalline, their solubility remains below 6.3 x 10(-8) M. No evidence for aqueous metal selenide colloids nor for Se sorption to colloidal phases was found. Since FeII phases like the ones investigated here should be ubiquitous in the near field of nuclear waste disposals as well as in the surrounding aquifers, mobility of the fission product 79Se may be much lower than previously assumed.     

Evaluation of environmental impacts of Integrated Industrial Estate��Pantnagar through application of air and water quality indices

Large-scale industrialization, population inflow, and rapid urbanization coupled with unfavorable meteorological conditions often induce significant degradation of urban environment. In order to assess the extent of environmental impacts due to establishment of the Integrated Industrial Estate??Pantnagar (IIE-Pantnagar), ambient air and groundwater were monitored from June 2007 to May 2008. Collected baseline information was normalized and interpreted with the application of air (AQI) and water quality indices (WQI). Among the pre-identified air pollutants, suspended particulate matter was found to be the principal culprit to deteriorate ambient air quality, with a maximum annual concentration of 418.5 ??g/m³. Monthly average concentrations of respirable particulate matter (aerodynamic diameter < 10 ??m) also persist at a critical level with an annual maximum of 207.3 ??g/m³. A segmented linear function with maximum operator concept was used to compute AQI, and the developed index was found well suitable to demonstrate temporal variations of ambient air quality. The computed AQI value for the selected study region varied from moderate (97.0) to very poor pollution level (309.2) in respect to developed air quality standards. Furthermore, an integrated WQI was developed comprising 9 parameters, and among all the 10 pre-identified locations, the average groundwater quality was found acceptable in terms of Indian drinking water standards. The maximum WQI (70.6) was found at the Kichha Railway Station during summer months, revealing moderate pollution load. Industrial discharge from IIE-Pantnagar coupled with other industrial setup may hold responsible for such kind of degradation of water quality. In contrast, WQI computed at Rudrapur City demonstrate minimum (15.0?C22.1) pollution load. For 95% of the monitoring period, the computed WQI was found acceptable for all selected locations with few exceptions. The application of WQI to assess temporal variations in groundwater quality was therefore found satisfactory.